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Pressure from molecular collisions

Intermediate

Gas pressure arises from momentum transfer to walls.

Key relationP = ⅓ρ⟨v²⟩

Each molecule hitting a wall transfers momentum 2mv_x. Averaging over huge numbers gives P = ⅓ρ⟨v²⟩ = ⅓(N/V)m⟨v²⟩.

Worked example

Air at 1 atm: about 10²⁷ collisions per m² each second.

Common mistake

Pressure is from the average, not a single hit.

In more detail

Gas pressure arises from molecules colliding with container walls and changing their momentum. Averaging over many collisions gives a steady pressure P = ⅓ρ⟨v²⟩.

Real-world uses

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Frequently asked questions

Why is pressure steady if collisions are random?

Because there are enormous numbers of collisions every second.

Does pressure depend on temperature?

Yes, because faster molecules hit the walls harder and more often.

Why does gas pressure increase when I heat it?

The molecules move faster, so they hit the walls harder and more often, raising the pressure.

Related topics in Kinetic Theory & Statistical Physics

Molecular picture of matter · Brownian motion · Ideal gas assumptions · Kinetic interpretation of temperature · Boltzmann constant · RMS speed

← All Kinetic Theory & Statistical Physics topics