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Debye model

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Phonons explain low-temperature heat capacity.

Key relationC ∝ T³

Treats lattice vibrations as quantised sound waves (phonons) with a cutoff frequency. It predicts C ∝ T³ at low temperature.

Worked example

Matches measurements of insulators near 10 K.

Common mistake

Electrons add a linear term in metals.

In more detail

The Debye model explains the specific heat of solids at low temperatures, predicting that it rises with the cube of temperature. It treats atomic vibrations as sound waves with a maximum frequency.

Real-world uses

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Frequently asked questions

What is the Debye temperature?

A characteristic temperature that marks where quantum effects become important for vibrations.

Why does heat capacity drop at low temperature?

Because fewer vibrational modes are excited when energy is low.

Why does the heat capacity fall at low temperature?

Quantum vibrations freeze out, so only the lowest-energy vibrations can store heat.

Related topics in Kinetic Theory & Statistical Physics

Bose–Einstein condensate · Fermi energy · Specific heat of solids · Photon gas · Planck distribution · Random walks

← All Kinetic Theory & Statistical Physics topics