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Hydrogen-like ions

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Energy scales as Z².

Ions with one electron (He⁺, Li²⁺) have E_n = −13.6 Z²/n² eV and radii a₀n²/Z; spectral lines shift to shorter wavelength.

Worked example

He⁺ ground state: −54.4 eV.

Common mistake

Applies only to single-electron ions.

In more detail

Hydrogen-like ions have one electron, such as He⁺ or Li²⁺, and their energy levels scale with the square of the nuclear charge. They are used to test quantum theory.

Real-world uses

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Frequently asked questions

How do their energies compare with hydrogen?

They scale with Z squared, so they are more tightly bound.

Why are they useful?

They are simpler than multi-electron atoms, giving clearer tests of theory.

Why does the energy depend on Z squared?

A higher nuclear charge pulls the electron more strongly, so its binding energy grows with the square of Z.

Related topics in Atomic & Nuclear Physics

Nuclear magnetic resonance · Mössbauer effect · Nuclear waste · Positronium · Muonic atoms · Atomic clocks

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