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Moseley's law

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X-ray frequency relates to atomic number.

√f ∝ (Z − b) for characteristic X-ray lines; it showed that atomic number, not mass, orders the elements, and predicted missing elements.

Worked example

Corrected the periodic table.

Common mistake

b ≈ 1 for K_α lines.

In more detail

Moseley's law relates the frequency of characteristic X-rays to the atomic number Z, showing that the square root of the frequency is roughly proportional to Z minus one.

Real-world uses

Open the interactive lesson, with simulation and quiz →

Frequently asked questions

Why was it important?

It showed that atomic number, not atomic mass, determines element identity.

Who discovered it?

Henry Moseley, in 1913.

Why is atomic number more fundamental than mass?

Atomic number counts the protons, which decides the chemistry, while mass can vary between isotopes.

Related topics in Atomic & Nuclear Physics

Franck–Hertz experiment · Characteristic X-rays · Continuous X-ray spectrum · X-ray diffraction · Electron configuration · Atomic mass unit

← All Atomic & Nuclear Physics topics